The successful implementation of this project has lead to a number of new [2.2]paracyclophane carboxylic linkers, which were used in the synthesis of new Metal-Organic Frameworks - porous crystallin materials made up of organic linkers and metal nodes. Several new MOF structures were obtained and characterized and their gas-storage capabilities were assessed. The results obtained within this project were the subject of three papers and one poster, presented at a national symposium. A fourth paper is currently underway and is estimated to be published by the end of 2022.
Papers:
- L. G. Bahrin, H. Hopf, P. G. Jones, L. M. Birsa, L. G. Sarbu, An Approach to Paracyclophane-Based Tetrathiafulvalenes: Synthesis and Characterization of a Pseudo-Geminal [2.2]Paracyclophane 1,3-Dithia-2-Thione, Molecules, 2020, 25, 5262, doi: 10.3390/molecules25225262
- Bahrin, L. G., Nicolescu, A., Shova, S., Marangoci, N. L., Birsa, L. M., Sarbu, L. G. Nitrogen-Based Linkers with a Mesitylene Core: Synthesis and Characterization, Molecules, 2021, 26, 5952, doi: 10.3390/molecules26195952
- Bejan, D., Dascalu, I. A., Shova, S., Trandabat, A. F., Bahrin, L. G. Mesitylene Tribenzoic Acid as a Linker for Novel Zn/Cd Metal-Organic Frameworks, Materials, 2022, 15, 4247, doi: 10.3390/ma15124247
Scientific events:
- Bahrin, L. G., Hopf, H. [2.2]PARACYCLOPHANE-BASED LINKERS FOR MOF SYNTHESIS, Simpozionul Național de Chimie, Ediția a XIII-a, 27 Noiembrie 2021, Craiova, Romania, http://chimie.ucv.ro/snchcv2021/
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